There are two ways to express the concentration of pollutants in the atmospheric environment:
(1) Mass concentration expression: that is, the mass number of pollutants contained in every cubic meter of air (mg/m³), the conversion relationship:
mg/m³ = μg/L
μg/m³ = ng/L
ng/m³ = pg/L
(2) Volume concentration expression: that is, the volume of pollutants contained in one million volumes of air (ppn), conversion relationship:
1 ppm (parts per million) = 1×10⁻⁶
1 ppb (parts per billion) = 1×10⁻⁹
1 ppt (parts per trillion) = 1×10⁻¹²
Using the mass concentration unit (mg/m³) as the expression method of air pollutant concentration can easily calculate the true amount of pollutants, but it is affected by temperature and pressure environmental conditions; the volume concentration (ppm/ppb) is the volume ratio, so there is no such problem.
Conversion formula between mass unit (μg/m³) and ppb:
Y(μg/m³) = X(ppb) × M/22.4/K
K = (273+T)/273
In 101325 Pa, at 23℃, the conversion of gas concentration is as follows:
Chemical name | Gas molecular weight M | 1 ppb → μg/m³ | 1 μg/m³ → ppb |
F⁻ | 19.0 | 0.78 | 1.28 |
Cl⁻ | 35.5 | 1.46 | 0.68 |
NO₂⁻ | 46.0 | 1.89 | 0.53 |
NO₃⁻ | 62.0 | 2.55 | 0.39 |
SO₄²⁻ | 96.0 | 3.95 | 0.25 |
B | 10.8 | 0.44 | 2.25 |
NH₄⁺ | 18.0 | 0.74 | 1.35 |
C₆H₅CH₃ | 92.0 | 3.79 | 0.26 |